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Ask iit jee aieee pet cbse icse state board community Discussion Response Post to: Mech. for Riemer Tiemann reaction
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Ankur Verma (656)

Olaaa!! Perrrfect answer. 112  [160 rates]

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CHCl3 (1) reacts with strong base to form the chloroform carbanion (2), which will quickly alpha-eliminate to give dichlorocarbene (3). Dichlorocarbene will react in the ortho- and para- position of the phenate (5) to give the dichloromethyl substituted phenol (7). After basic hydrolysis, the desired product (9) is formed.
The mechanism of the Reimer-Tiemann reaction
 
 
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