become expert | help | login
refer a friend - earn nickels!!
 advanced

  Ask & Discuss Questions with Community & Experts

Moderation Team
  500 chars left
Ask experts Expert Question: Why tautomerism is not possible in case of p-benzoquinone
Reply Forum Index -> Organic Chemistry originally posted here on IIT-JEE / AIEEE community   
Email  
Author Message
Aman sharma (0)

Olaaa!! Perrrfect answer. 0  [0 rates]

Aman sharma's Avatar

total posts: 7    
Offline
Why tautomerism is not possible in case of p-benzoquinone
    
Krishna Gopal Singh (4618)

Forum Expert

Olaaa!! Perrrfect answer. 738  bad job dude!! I dont approve of this answer! 2  [1206 rates]

Krishna Gopal Singh's Avatar

total posts: 5153    
Offline
If p-benzoquinone toutomerize the carbon next C=O group will have to change from sp2 to sp3. This will produce a lot of ring strain and will remove aromaticity of benzene ring. That is why it does not show toutomerism.
  this reply:   0 points  (with Olaaa!! Perrrfect answer.   in 0   votes   )     [?]
 
You have to be logged on to rate
  
AKILESH (0)

Olaaa!! Perrrfect answer. 0  [0 rates]

AKILESH's Avatar

total posts: 1    
Offline

 That means tautomerism and  the enol form exists but the equilibrium is highly towards the keto form .

This is different from the fact that tautomerism is not possible (say in the absence of all alpha hydrogens)

  this reply:   0 points  (with Olaaa!! Perrrfect answer.   in 0   votes   )     [?]
 
You have to be logged on to rate
  
 
reply Forum Index -> Organic Chemistry
Go to: 
Sponsored Links
preparing GATE 2010?
solved, model Papers,study Material
courses from Brilliant. Buy Now !

goiit.com/Brilliant-GATE

preparing GATE ?
online, Brilliant Tutorial courses
solved, model papers. Buy Now!

gateprep.com/GATE

preparing for IAS ?
Brilliant Tutorial's correspondence
Complete course. Buy Online Now !

goiit.com/Brilliant-UPSC-postal

preparing IES ?
solved, model paper, prelim monitor
online, study material. Buy Online!

go4ias.com/IES

preparing for BSNL JTO ?
solved, model paper, rank predictor
online, study material. Buy Online!

go4ias.com/BSNL-JTO