become expert | help | login
refer a friend - earn nickels!!
 advanced
originally posted here on IIT-JEE / AIEEE community   
like the article? email it to a friend.  email this article!  
   Mesomers are optically inactive. why ??
posted on 9 Oct 2010 14:28:20 IST    1593 views    8 comments
« Back to Articles
Tagged with:   Awaiting Review for Nickels

     WHY MESO COMPOUNDS ARE OPTICALLY INACTIVE   ??????

 

Meso means middle, half of the molecule is the mirror image of the other half.


As a result of it, one chiral center will rotate the plane polarized light in one direction and the other chiral center will cancel that rotation by rotating the plane polarized light by the same magnitude, but opposite direction.


Thus the resultant rotation is zero and meso compounds do not rotate the plane polarized light. They are optically inactive. Meso compounds can be recognized by the fact that they have two or more chiral centers and a plane of symmetry.

Thus if a compound has a plane of symmetry it may not be optically active even though it possesses chiral centers..

Ex...

 

Not copy pasted......

self written..........

coment if u like........

let me knw if I commit any mistake....

About the Author:
ThIrStY of IIT (936)

Olaaa!! Perrrfect answer.  174  [207 rates]

ThIrStY of IIT's Avatar

total posts: 380    
online Offline
  this article:   25 points  (with Olaaa!! Perrrfect answer.   in 5   votes   )     [?]
 
You have to be logged on to rate
  
LIVING  FOR    DYING(  cash machine... ) is offline comment by LIVING FOR DYING( cash machine... )      (posted on 9 Oct 2010 16:45:42 IST)
    dude m not intyrested in che......if u awnt to get rated then post some stuff related to phy,,maths.....show this to geet she knows che. better than me.......nyways i m rating it
Ria   is offline comment by Ria      (posted on 9 Oct 2010 16:54:07 IST)
    adding to this a compound having centre of symmetry can also be optically active....
Ria   is offline comment by Ria      (posted on 9 Oct 2010 16:54:43 IST)
    sorry inactive
ThIrStY of IIT is offline comment by ThIrStY of IIT      (posted on 9 Oct 2010 20:41:34 IST)
    hey! @living for dying my intention is not to get rated,,, I want to know they r correct or not?
Geet is offline comment by Geet      (posted on 10 Oct 2010 10:42:59 IST)
    The stereoisomer which is not chiral or dissymetric eventhough it contains two chiral carbon atoms is a mesomer. Such an optically inactive compound whose molecule is superimposable on its mirror image inspite of the presence of chiral carbon is a meso compound. or meso isomer or mesomer.
LIVING  FOR    DYING(  cash machine... ) is offline comment by LIVING FOR DYING( cash machine... )      (posted on 11 Oct 2010 13:12:23 IST)
    @ thristy......i think now u got wt u wnt....
Naveen thakur is offline comment by Naveen thakur      (posted on 17 Oct 2011 02:08:51 IST)
    

 I understand that very easily

abhishek kumar is offline comment by abhishek kumar      (posted on 17 Oct 2011 12:11:08 IST)
    thanks i like it but we can also solve it by first finding plane of symmetry and then by using R and S tool
Sponsored Links
preparing GATE 2010?
solved, model Papers,study Material
courses from Brilliant. Buy Now !

goiit.com/Brilliant-GATE

preparing GATE ?
online, Brilliant Tutorial courses
solved, model papers. Buy Now!

gateprep.com/GATE

preparing for IAS ?
Brilliant Tutorial's correspondence
Complete course. Buy Online Now !

goiit.com/Brilliant-UPSC-postal

preparing IES ?
solved, model paper, prelim monitor
online, study material. Buy Online!

go4ias.com/IES

preparing for BSNL JTO ?
solved, model paper, rank predictor
online, study material. Buy Online!

go4ias.com/BSNL-JTO